最近の論文recent publications


Most Recent Publications

Dynamic behavior and alkyne insertion reactions of alkenyl- and thiolate-bridged diiron carbonyl complexes
Chisato Murata, Kyohei Kobayashi, Hiroshi Nakajima, Isamu Kinoshita, Sakie Sakai, Masakazu Hirotsu
J. Organomet. Chem., 2023, 997, 122766. DOI: 10.1016/j.jorganchem.2023.122766

Red-light responsive photoCORM activated in aqueous acid solution
Natsuo Nomura, Seiya Tanaka, Masakazu Hirotsu, Takanori Nishioka, Hiroshi Nakajima
J. Organomet. Chem., 2023, 984, 122578. DOI: 10.1016/j.jorganchem.2022.122578

Crystal structures and electrochemical properties of nickel(II) complexes with N,N',N'',S-tetradentate Schiff base ligands
Masakazu Hirotsu, Junhei Sanou, Toyotaka Nakae, Takumi Matsunaga, Isamu Kinoshita
Acta Cryst., 2022, E78, 500-505. DOI: 10.1107/S2056989022003954

Synthesis of iron(III)-carbonyl complex with variable wavelength range for CO release depending on protonation and deprotonation of axial phosphorous ligands
Seiya Tanaka, Natsuo Nomura, Takanori Nishioka, Masakazu Hirotsu, Hiroshi Nakajima
J. Organomet. Chem., 2021, 943, 121843. DOI: 10.1016/j.jorganchem.2021.121843

Representative Publications

Iron Carbonyl Complexes Containing N,C,S-Tridentate Ligands with Quinoline, Vinyl, and Benzenethiolate Units
Yuta Masuda, Yuki Yagami, Kotomi Nakazawa, Masakazu Hirotsu
Organometallics, 2020, 39 (22), 4051-4060. DOI: 10.1021/acs.organomet.0c00621

Tetra- and dinuclear manganese complexes of xanthene-bridged O,N,O-Schiff bases with 3-hydroxypropyl or 2-hydroxybenzyl groups: ligand substitution at a triply bridging site
Rina Ogawa, Takayoshi Suzuki, Masakazu Hirotsu, Noriyuki Nishi, Yuu Shimizu, Yukinari Sunatsuki, Yoshio Teki, Isamu Kinoshita
Dalton Trans., 2019, 48 (36), 13622-13629. DOI: 10.1039/c9dt03007g

CO Release from N,C,S-Pincer Iron(III) Carbonyl Complexes Induced by Visible-to-NIR Light Irradiation: Mechanistic Insight into Effects of Axial Phosphorus Ligands
Toyotaka Nakae, Masakazu Hirotsu, Hiroshi Nakajima
Inorg. Chem., 2018, 57 (14), 8615-8626. DOI: 10.1021/acs.inorgchem.8b01407

Iron carbonyl complexes of N,C,S-pincer ligands with a pendant thioether arm: Synthesis, structures and reactivity
Masakazu Hirotsu, Kiyokazu Santo, Yui Tanaka, Isamu Kinoshita
Polyhedron, 2018, 143, 201-208. DOI: 10.1016/j.poly.2017.10.014

Carbon-Sulfur Bond Cleavage Reactions of Quinolyl-Substituted Thiophenes with Iron Carbonyls
Takumi Matsunaga, Isamu Kinoshita, Masakazu Hirotsu
Organometallics, 2017, 36 (11), 2228-2236. DOI: 10.1021/acs.organomet.7b00280

Visible-light-induced release of CO by thiolate iron(III) carbonyl complexes bearing N,C,S-pincer ligands
Toyotaka Nakae, Masakazu Hirotsu, Shigetoshi Aono, Hiroshi Nakajima
Dalton Trans., 2016, 45 (41), 16153-16156. DOI: 10.1039/c6dt03399g

Fluorescence behaviour of an anthracene-BODIPY system affected by spin states of a dioxolene-cobalt centre
Koichi Katayama, Masakazu Hirotsu, Akitaka Ito, Yoshio Teki
Dalton Trans., 2016, 45 (25), 10165-10172. DOI: 10.1039/c6dt00864j

Di- and Mononuclear Iron Complexes of N,C,S-Tridentate Ligands Containing an Aminopyridyl Group: Effect of the Pendant Amine Site on Catalytic Properties for Proton Reduction
Toyotaka Nakae, Masakazu Hirotsu, Isamu Kinoshita
Organometallics, 2015, 34 (16), 3988-3997. DOI: 10.1021/acs.organomet.5b00366

Formation of Acyl and Dioxycarbene Ruthenium Complexes via Double C-S Bond Cleavage and CO Insertion
Kiyokazu Santo, Masakazu Hirotsu, Keisuke Kawamoto, Takanori Nishioka, Isamu Kinoshita
Bull. Chem. Soc. Jpn., 2015, 88 (4), 613-615. DOI: 10.1246/bcsj.20140379

Formation, reactivity and redox properties of carbon- and sulfur-bridged diiron complexes derived from dibenzothienyl Schiff bases: effect of N,N- and N,P-chelating moieties
Kiyokazu Santo, Masakazu Hirotsu, Isamu Kinoshita
Dalton Trans., 2015, 44 (9), 4155-4166. DOI: 10.1039/c4dt03422h

Diiron Carbonyl Complexes Bearing an N,C,S-Pincer Ligand: Reactivity toward Phosphines, Heterolytic Fe-Fe Cleavage, and Electrocatalytic Proton Reduction
Masakazu Hirotsu, Kiyokazu Santo, Chiaki Tsuboi, Isamu Kinoshita
Organometallics, 2014, 33 (16), 4260-4268. DOI: 10.1021/om500558h

Synthesis, magnetic properties and dynamic behavior of cobalt complexes with an anthracene-containing dioxolene ligand
Koichi Katayama, Masakazu Hirotsu, Isamu Kinoshita, Yoshio Teki
Dalton Trans., 2014, 43 (35), 13384-13391. DOI: 10.1039/c4dt01574f

Skeletal Modification of Benzothiophene Mediated by Iron Carbonyls: Insertion of Terminal Alkynes with Migration of Amino and Alkoxy Groups
Kyohei Kobayashi, Masakazu Hirotsu, Isamu Kinoshita
Organometallics, 2013, 32 (18), 5030-5033. DOI: 10.1021/om400734s

Titanium and manganese complexes supported by a xanthene-bridged bis(tripodal N2O2) ligand: isomerization, intramolecular hydrogen bonding and metal-binding ability
Masakazu Hirotsu, Keisuke Kawamoto, Rika Tanaka, Yuji Nagai, Keiji Ueno, Yoshio Teki, Isamu Kinoshita
Dalton Trans., 2013, 42 (34), 12220-12227. DOI: 10.1039/c3dt51389k

Carbon- and Sulfur-Bridged Diiron Carbonyl Complexes Containing N,C,S-Tridentate Ligands Derived from Functionalized Dibenzothiophenes: Mimics of the [FeFe]-Hydrogenase Active Site
Masakazu Hirotsu, Kiyokazu Santo, Hideki Hashimoto, Isamu Kinoshita
Organometallics, 2012, 31 (21), 7548-7557. DOI: 10.1021/om300826y

Anion-Controlled Assembly of Four Manganese Ions: Structural, Magnetic, and Electrochemical Properties of Tetramanganese Complexes Stabilized by Xanthene-Bridged Schiff Base Ligands
Masakazu Hirotsu, Yuu Shimizu, Naoto Kuwamura, Rika Tanaka, Isamu Kinoshita, Ryoichi Takada, Yoshio Teki, Hideki Hashimoto
Inorg. Chem., 2012, 51 (2), 766-768. DOI: 10.1021/ic202287k

Design, synthesis, magnetic properties of a π-radical ligand with photo-excited high-spin state and its Fe(II) complex. The first stage of a new strategy for LIESST materials
Koichi Katayama, Masakazu Hirotsu, Isamu Kinoshita, Yoshio Teki
Dalton Trans., 2012, 41 (1), 13465-13473. DOI: 10.1039/c2dt31831h

Sulfur-Bridged Ta-M (M = Mo, Cr) Multinuclear Complexes Bearing a Four-Electron-Reduced Dinitrogen Ligand
Ryoichi Takada, Masakazu Hirotsu, Takanori Nishioka, Hideki Hashimoto, Isamu Kinoshita
Organometallics, 2011, 30 (16), 4232-4235. DOI: 10.1021/om200596v

Carbon-sulfur bond cleavage reactions of dibenzothiophene derivatives mediated by iron and ruthenium carbonyls
Masakazu Hirotsu, Chiaki Tsuboi, Takanori Nishioka, Isamu Kinoshita
Dalton Trans., 2011, 40 (4), 785-787. DOI: 10.1039/c0dt00768d

Manganese(II), Nickel(II), and Palladium(II) Complexes of a Terpyridine-Like Ligand Containing a Sulfur Linkage, and an Analogous NCN Pincer Palladium(II) Complex: Synthesis, Characterization, and Pd-Catalyzed Reactions
Masakazu Hirotsu, Yuhei Tsukahara, Isamu Kinoshita
Bull. Chem. Soc. Jpn., 2010, 83 (9), 1058-1066. DOI: 10.1246/bcsj.20100076

Synthesis and characterization of xanthene-bridged Schiff base dimanganese(III) complexes: bimetallic catalysts for asymmetric oxidation of sulfides
Masakazu Hirotsu, Naoki Ohno, Takashi Nakajima, Chie Kushibe, Keiji Ueno, Isamu Kinoshita
Dalton Trans., 2010, 39 (1), 139-148. DOI: 10.1039/b909491a

Steric, geometrical and solvent effects on redox potentials in salen-type copper(II) complexes
Masakazu Hirotsu, Naoto Kuwamura, Isamu Kinoshita, Masaaki Kojima, Yuzo Yoshikawa, Keiji Ueno
Dalton Trans., 2009 (37), 7678-7683. DOI: 10.1039/b906013h

Ruthenium and Rhodium Complexes with Thiolate-Containing Pincer Ligands Produced by C-S Bond Cleavage of Pyridyl-Substituted Dibenzothiophenes
Mayuko Shibue, Masakazu Hirotsu, Takanori Nishioka, Isamu Kinoshita
Organometallics, 2008, 27 (17), 4475-4483. DOI: 10.1021/om8003916

Full List of Publications

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